I think I ended up narrowing down the issue. My apologies as it seems to have been setting related (I was driving my new NEMA23 way too fast according to the reprap firmware EMF calculator), I backed off the maximum speed and my problem seems to have resolved itself. Thank you all for your suggestions and help.

Best posts made by DukeMachine
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RE: Odd arc behaviour
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RE: Gcode On the Duet3 Behaving Unpredictably
@T3P3Tony My machine does have the ability to home, but due to the nature of the beast I need to start the embroidery at a point other than machine home, so I just set a relative 0,0 position wherever I need to embroider. Attached a picture for reference.
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RE: Hotend Thermistor Issues
Well confirmed, heater cartridge needed to be replaced. Thanks for the help.
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RE: Gcode On the Duet3 Behaving Unpredictably
@T3P3Tony That did it. Dumb mistake on my part
. Thanks for the assist.