The output of the Orion is active low.
Paul and I went through all the trouble shooting steps I could think of last night. He measured voltages of 3.233 untriggered and 0v triggered. This is at the Orion end of the cable, however, since the Orion uses an open drain output, a broken cable would result in a floating pin that normally measures ~0.5v. He also tried with three different cables.
What's really puzzling to me is what's shown in the video, the Orion triggers lighting the blue LED but the bed keeps moving. If there were an issue with the sensitivity of the Orion or its triggering then I would expect to see the bed hit the nozzle, keep moving, and then have the Orion trigger. It appears that the Duets response to the trigger signal is delayed for some reason.
Idris