@dragonn I know the EMF calculator. It was probably the most visited webpage in my browser's history for quite a while while I was selecting new motors for my printer. 😁
@deckingman I think your idea is the better approach here. Also currently this is all in the just-wanna-have-it stage. I have absolutely no need for a MPCNC I would just build it to have it built.
And you are right, peripherals are (in my experience) more widely available for 12V than for 24V.
I am going to mark this question as solved with: 24V is always better for your steppers because they could run faster than with 12V. And a buck-down converter can always take 24V to 12V in case of peripherals not available at native 24V.