Glad you figured it out TimVukman.
I wasn't trying to hijack you thread, I thought maybe our problems were related.
I guess not.
I figured out my problem as well, maybe this will help someone else.
When I formatted to Fat32, there was 16MB of space being left unallocated. That would screw the Duet up and wouldn't read the SD card correctly. It could see it mounted in slot zero, but that is it.
What I did to fix the SD card was run DiskPart, select and clean that drive, then create a primary partition.
Then formatted to Fat32 and was good to go.